The Structure of the Atom

There is general agreement amongst all chemists, physicists, and mathematicians upon the conclusions which we have so far given. We know that the atoms of matter are constantly—either spontaneously or under stimulation—giving off electrons, or breaking up into electrons; and they therefore contain electrons. Thus we have now complete proof of the independent existence of atoms and also of electrons.

When, however, the man of science tries to tell us how electrons compose atoms, he passes from facts to speculation, and very difficult speculation. Take the letter “o” as it is printed on this page. In a little bubble of hydrogen gas no larger than that letter there are trillions of atoms; and they are not packed together, but are circulating as freely as dancers in a ball-room. We are asking the physicist to take one of these minute atoms and tell us how the still smaller electrons are arranged in it. Naturally he can only make mental pictures, guesses or hypotheses, which he tries to fit to the facts, and discards when they will not fit.

At present, after nearly twenty years of critical discussion, there are two chief theories of the structure of the atom. At first Sir J. J. Thomson imagined the electrons circulating in shells (like the layers of an onion) round the nucleus of the atom. This did not suit, and Sir E. Rutherford and others worked out a theory that the electrons circulated round a nucleus rather like the planets of our solar system revolving round the central sun. Is there a nucleus, then, round which the electrons revolve? The electron, as we saw, is a disembodied atom of electricity; we should say, of “negative” electricity. Let us picture these electrons all moving round in orbits with great velocity. Now it is suggested that there is a nucleus of “positive” electricity attracting or pulling the revolving electrons to it, and so forming an equilibrium, otherwise the electrons would fly off in all directions. This nucleus has been recently named the proton. We have thus two electricities in the atom: the positive = the nucleus; the negative = the electron. Of recent years Dr. Langmuir has put out a theory that the electrons do not revolve round the nucleus, but remain in a state of violent agitation of some sort at fixed distances from the nucleus.

PROFESSOR SIR J. J. THOMSON

Experimental discoverer of the electronic constitution of matter, in the Cavendish Physical Laboratory, Cambridge. A great investigator, noted for the imaginative range of his hypotheses and his fertility in experimental devices.

From the Smithsonian Report, 1915.

ELECTRONS PRODUCED BY PASSAGE OF X-RAYS THROUGH AIR

A photograph clearly showing that electrons are definite entities. As electrons leave atoms they may traverse matter or pass through the air in a straight path The illustration shows the tortuous path of electrons resulting from collision with atoms.

MAGNETIC DEFLECTION OF RADIUM RAYS

The radium rays are made to strike a screen, producing visible spots of light. When a magnetic field is applied the rays are seen to be deflected, as in the diagram. This can only happen if the rays carry an electric charge, and it was by experiments of this kind that we obtained our knowledge respecting the electric charges carried by radium rays.

Reproduced by permission of “Scientific American.”

PROFESSOR R. A. MILLIKAN’S APPARATUS FOR COUNTING ELECTRONS

But we will confine ourselves here to the facts, and leave the contending theories to scientific men. It is now pretty generally accepted that an atom of matter consists of a number of electrons, or charges of negative electricity, held together by a charge of positive electricity. It is not disputed that these electrons are in a state of violent motion or strain, and that therefore a vast energy is locked up in the atoms of matter. To that we will return later. Here, rather, we will notice another remarkable discovery which helps us to understand the nature of matter.

A brilliant young man of science who was killed in the war, Mr. Moseley, some years ago showed that, when the atoms of different substances are arranged in order of their weight, they are also arranged in the order of increasing complexity of structure. That is to say, the heavier the atom, the more electrons it contains. There is a gradual building up of atoms containing more and more electrons from the lightest atom to the heaviest. Here it is enough to say that as he took element after element, from the lightest (hydrogen) to the heaviest (uranium) he found a strangely regular relation between them. If hydrogen were represented by the figure one, helium by two, lithium three, and so on up to uranium, then uranium should have the figure ninety-two. This makes it probable that there are in nature ninety-two elements—we have found eighty-seven—and that the number Mr. Moseley found is the number of electrons in the atom of each element; that is to say, the number is arranged in order of the atomic numbers of the various elements.

The New View of Matter

Up to the point we have reached, then, we see what the new view of Matter is. Every atom of matter, of whatever kind throughout the whole universe, is built up of electrons in conjunction with a nucleus. From the smallest atom of all—the atom of hydrogen—which consists of one electron, rotating round a positively charged nucleus, to a heavy complicated atom, such as the atom of gold, constituted of many electrons and a complex nucleus, we have only to do with positive and negative units of electricity. The electron and its nucleus are particles of electricity. All Matter, therefore, is nothing but a manifestation of electricity. The atoms of matter, as we saw, combine and form molecules. Atoms and molecules are the bricks out of which nature has built up everything; ourselves, the earth, the stars, the whole universe.

But more than bricks are required to build a house. There are other fundamental existences, such as the various forms of energy, which give rise to several complex problems. And we have also to remember, that there are more than eighty distinct elements, each with its own definite type of atom. We shall deal with energy later. Meanwhile it remains to be said that, although we have discovered a great deal about the electron and the constitution of matter, and that while the physicists of our own day seem to see a possibility of explaining positive and negative electricity, the nature of them both is unknown. There exists the theory that the particles of positive and negative electricity, which make up the atoms of matter, are points or centres of disturbances of some kind in a universal ether, and that all the various forms of energy are, in some fundamental way, aspects of the same primary entity which constitutes matter itself.

But the discovery of the property of radio-activity has raised many other interesting questions, besides that which we have just dealt with. In radio-active elements, such as uranium for example, the element is breaking down; in what we call radio-activity we have a manifestation of the spontaneous change of elements. What is really taking place is a transmutation of one element into another, from a heavier to a lighter. The element uranium spontaneously becomes radium, and radium passes through a number of other stages until it, in turn, becomes lead. Each descending element is of lighter atomic weight than its predecessor. The changing process, of course, is a very slow one. It may be that all matter is radio-active, or can be made so. This raises the question whether all the matter in the universe may not undergo disintegration.

There is, however, another side of the question, which the discovery of radio-activity has brought to light, and which has effected a revolution in our views. We have seen that in radio-active substances the elements are breaking down. Is there a process of building up at work? If the more complicated atoms are breaking down into simpler forms, may there not be a converse process—a building up from simpler elements to more complicated elements? It is probably the case that both processes are at work.

There are some eighty-odd chemical elements on the earth to-day: are they all the outcome of an inorganic evolution, element giving rise to element, going back and back to some primeval stuff from which they were all originally derived infinitely long ago? Is there an evolution in the inorganic world which may be going on, parallel to that of the evolution of living things; or is organic evolution a continuation of inorganic evolution? We have seen what evidence there is of this inorganic evolution in the case of the stars. We cannot go deeply into the matter here, nor has the time come for any direct statement that can be based on the findings of modern investigation. Taking it altogether the evidence is steadily accumulating, and there are authorities who maintain that already the evidence of inorganic evolution is convincing enough. The heavier atoms would appear to behave as though they were evolved from the lighter. The more complex forms, it is supposed, have evolved from the simpler forms. Moseley’s discovery, to which reference has been made, points to the conclusion that the elements are built up one from another.

Other New Views

We may here refer to another new conception to which the discovery of radio-activity has given rise. Lord Kelvin, who estimated the age of the earth at twenty million years, reached this estimate by considering the earth as a body which is gradually cooling down, “losing its primitive heat, like a loaf taken from the oven, at a rate which could be calculated, and that the heat radiated by the sun was due to contraction.” Uranium and radio-activity were not known to Kelvin, and their discovery has upset both his arguments. Radio-active substances, which are perpetually giving out heat, introduce an entirely new factor. We cannot now assume that the earth is necessarily cooling down; it may even, for all we know, be getting hotter. At the 1921 meeting of the British Association, Professor Rayleigh stated that further knowledge had extended the probable period during which there had been life on this globe to about one thousand million years, and the total age of the earth to some small multiple of that. The earth, he considers, is not cooling, but “contains an internal source of heat from the disintegration of uranium in the outer crust.” On the whole the estimate obtained would seem to be in agreement with the geological estimates. The question, of course, cannot, in the present state of our knowledge, be settled within fixed limits that meet with general agreement.

MAKING THE INVISIBLE VISIBLE

Radium, as explained in the text, emits rays—the “Alpha,” the “Beta” (electrons), and “Gamma” rays. The above illustration indicates the method by which these invisible rays are made visible, and enables the nature of the rays to be investigated. To the right of the diagram is the instrument used, the Spinthariscope, making the impact of radium rays visible on a screen.

The radium rays shoot out in all directions; those that fall on the screen make it glow with points of light. These points of light are observed by the magnifying lens.

A. Magnifying lens. B. A zinc sulphite screen. C. A needle on whose point is placed a speck of radium.

The lower picture shows the screen and needle magnified..

THE THEORY OF ELECTRONS

An atom of matter is composed of electrons. We picture an atom as a sort of miniature solar system, the electrons (particles of negative electricity) rotating round a central nucleus of positive electricity, as described in the text. In the above pictorial representation of an atom the whirling electrons are indicated in the outer ring. Electrons move with incredible speed as they pass from one atom to another.

ARRANGEMENTS OF ATOMS IN A DIAMOND

The above is a model (seen from two points of view) of the arrangement of the atoms in a diamond. The arrangement is found by studying the X-ray spectra of the diamond.

As we have said, there are other fundamental existences which give rise to more complex problems. The three great fundamental entities in the physical universe are matter, ether, and energy; so far as we know, outside these there is nothing. We have dealt with matter, there remain ether and energy. We shall see that just as no particle of matter, however small, may be created or destroyed, and just as there is no such thing as empty space—ether pervades everything—so there is no such thing as rest. Every particle that goes to make up our solid earth is in a state of perpetual unremitting vibration; energy “is the universal commodity on which all life depends.” Separate and distinct as these three fundamental entities—matter, ether, and energy—may appear, it may be that, after all, they are only different and mysterious phases of an essential “oneness” of the universe.

The Future

Let us, in concluding this chapter, give just one illustration of the way in which all this new knowledge may prove to be as valuable practically as it is wonderful intellectually. We saw that electrons are shot out of atoms at a speed that may approach 160,000 miles a second. Sir Oliver Lodge has written recently that a seventieth of a grain of radium discharges, at a speed a thousand times that of a rifle bullet, thirty million electrons a second. Professor Le Bon has calculated that it would take 1,340,000 barrels of powder to give a bullet the speed of one of these electrons. He shows that the smallest French copper coin—smaller than a farthing—contains an energy equal to eighty million horsepower. A few pounds of matter contain more energy than we could extract from millions of tons of coal. Even in the atoms of hydrogen at a temperature which we could produce in an electric furnace the electrons spin round at a rate of nearly a hundred trillion revolutions a second!

Every man asks at once: “Will science ever tap this energy?” If it does, no more smoke, no mining, no transit, no bulky fuel. The energy of an atom is of course only liberated when an atom passes from one state to another. The stored up energy is fortunately fast bound by the electrons being held together as has been described. If it were not so “the earth would explode and become a gaseous nebula”! It is believed that some day we shall be able to release, harness, and utilise atomic energy. “I am of opinion,” says Sir William Bragg, “that atom energy will supply our future need. A thousand years may pass before we can harness the atom, or to-morrow might see us with the reins in our hands. That is the peculiarity of Physics—research and ‘accidental’ discovery go hand in hand.” Half a brick contains as much energy as a small coal-field. The difficulties are tremendous, but, as Sir Oliver Lodge reminds us, there was just as much scepticism at one time about the utilisation of steam or electricity. “Is it to be supposed,” he asks, “that there can be no fresh invention, that all the discoveries have been made?” More than one man of science encourages us to hope. Here are some remarkable words written by Professor Soddy, one of the highest authorities on radio-active matter, in our chief scientific weekly (Nature, November 6, 1919):

If that “promise” is ever realised, the economic and social face of the world will be transformed.

Before passing on to the consideration of ether, light, and energy, let us see what new light the discovery of the electron has thrown on the nature and manipulation of electricity.